Aim To investigate the chemical constituents of Salvia cavaleriei Levi. var. erythrophylla (Hemsl.) Stib. Methods Compounds were isolated by silica gel column chromatography and Sephadex LH-20 gel column chromatography, and the structures were identified by spectral analysis. Result Five compounds were identified as 3β, 6β, 23-trihydroxyolean-12-en-28-oic acid (1), ursolic acid (2), n-heptadecanoic acid (3), n-octadecanoic acid (4), and β-sitosterol (5). Conclusion Five compounds were isolated from the plant for the first time.