Composites of high molecular weight polyaniline with various weight percentages of multi-walled carbon nanotubes(MWNTs) were synthesized in the presence of selected dissolved neutral salt by in situ polymerization.The composites were characterized by means of SEM,FTIR and XRD,four-point probe conductivity measurements.The results indicate that the composites possess very different morphologies,high electrical conductivities and good crystallization compared with high molecular weight polyaniline.