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国家自然科学基金(50473038)

作品数:4 被引量:44H指数:3
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Molecular Imprinting Fibrous Membranes of Poly(acrylonitrile-co-acrylic acid) Prepared by Electrospinning被引量:2
2006年
IntroductionOver the past few decades, molecular imprinting has been described as a technology for preparing "molecular doors" which can be matched to "template keys". It has been found to be a simple and effective approach to introduce specific recognition sites into synthetic polymers, namely, to create molecular imprinting polymers Remarkable features such as stability, ease of preparation and low cost, have made molecular imprinting polymers particularly attractive in chemical sensors, catalysis, drug delivery, and dedicated separations. Practical applications of molecular imprinting polymers require accessible sites, fast mass transfer, and quick binding. However, present techniques used to prepare molecular imprinting polymers most often result in materials exhibiting a high affinity and selectivity but a low capacity and poor site accessibility for the target molecules. It is also very difficult to remove the imprinted molecules located in these molecular imprinting polymers because the highly cross-linked structures do not allow the templates to move freely. To some extent, combining molecular imprinting technology with membrane separation and surface imprinting can overcome the shortcomings, such as mass transfer limitations and non-quantitative recovery of the template molecules seen for imprinted materials fabricated by conventional bulk methods. In that ease, it appears to us that molecular imprinting polymers with high surface area to volume ratios are particularly desirable for largescale applications. Eleetrospun nano and ultrafine fibrous membranes are the most suitable materials due to advantages such as: (1) large specific surfaces, providing relatively high imprinting sites per unit mass; (2) fine porous structures, resulting in the accessibility of imprinting sites and low diffusion resistance necessary for high efficiency; and (3) easy recoverability from practical operation or applicability for continuous usages. Therefore, in this work, we prepared a unique kind of imp
CHE Ai-fuYANG Yun-fengWAN Ling-shuWU JianXU Zhi-kang
关键词:ELECTROSPINNING
表面分子印迹研究进展被引量:32
2007年
为了拓展分子印迹聚合物(Molecularly Imprinted Polymers,MIP)的应用领域,表面分子印迹作为一种新的方法,受到了极大的关注。本文首先分析了MIP传统制备方法存在的问题;然后依据印迹位点所处位置的不同,分类综述了表面分子印迹的各种方法。
仰云峰车爱馥吴健徐志康
关键词:表面分子印迹聚合物膜传感器乳液聚合
高聚物负载卟啉铁的合成及其催化环己烷氧化反应研究被引量:6
2006年
在制备单氨基取代卟啉铁Fe(ATPP)Cl的基础上,以具有良好成膜特性的丙烯腈/丙烯酸共聚物为载体,通过氨基与羧基的缩合,得到新型的高聚物负载卟啉铁(Poly-Fe(ATPP)Cl).以分子氧-抗坏血酸-Poly-Fe(ATPP)Cl作为细胞色素P-450的氧化模拟体系,研究了其对环己烷在常温常压下温和氧化的催化性能,并考察反应时间、还原剂用量、轴向配体以及催化剂的回收利用等因素的影响.
马卡迪何洁吴健
关键词:环己烷催化氧化
基于金属卟啉的分子印迹聚合物的合成及其对三唑类杀菌剂识别性能研究被引量:5
2009年
以三唑类杀菌剂氟环唑为印迹分子,5-(4-甲基丙烯酰氧苯基)-10,15,20-三苯基卟啉锌为功能单体,乙二醇二甲基丙烯酸酯为交联剂,合成了新型的基于金属卟啉的分子印迹聚合物.紫外-可见光谱研究表明印迹分子与功能单体在聚合前形成1∶1配合物.通过选择性吸附和固相萃取表征研究了该印迹聚合物对氟环唑及具有类似化学结构的三唑类杀菌剂的识别能力,并与非印迹聚合物进行了比较,结果表明印迹聚合物具有良好的特异性识别性能,同时,印迹聚合物的交联度及吸附溶剂的极性对印迹效果有着显著影响.
曾庆斌吴健徐志康
关键词:分子印迹聚合物金属卟啉分子识别
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