The structure and properties of Mg-doped SrBi4Ti4O15(SBT) were dicussed. Mg substitution into SBT had two possibilities states with the dopant amount variety. Mg cation substituted mostly into Sr^2+ and the amount proportion was 68.11%.Mg ion will substitute into Ti ion site in perovskite layer when the doping amount increases. Polarization increases sharply when x=0.1 and then decreases becauses of the domain pinning. The Curie temperature of Mg-doped SBT is about 300 ℃ and there is a broad diffuse phase transition near Tc with a flat peak near the Ta of SBT.
The NaNbO3 powders were synthesized and their crystal structure changes were analyzed by ultrahigh pressure up to 6 GPa.The results indicate that the pure NaNbO3 powders can be synthesized at 300℃ under a pressure of 4 GPa, to sig- nificantly restrain the Na element volatilization compared with the traditional syn- thesis method. It is found that the crystal structure of synthesized NaNbO3 changes from low symmetry to high symmetry with the increase of the pressure.
CAO MingHe TIAN Wei LI MingFa SUN WenHua HU MingJi LIU HanXing
Amino-terminated polyethers and amino-terminated polyurethane were used as curing agent to cure the epoxy resin together and get a series of cured products. The damping properties of the composites were studied by DMA test at different measurement frequencies. Damping mechanical tests show that the flexible epoxy resin has higher loss factor than common epoxy. The highest loss factor reaches 1.57. Also the height and position of loss factor peak of the flexible epoxy resin varies by changing the content of amino-terminated polyethers. Results shows that the flexible epoxy resin can be used as damping polymer materials at room temperature or in common frequency range.
The effects of glass flit on the sintering and electric properties of PMN-PT textured ceramics were investigated. The glass frits, including PbO, Bi2O3 and ZnO, were selected since liquid phase sintering lowered the PMN-PT sintering temperature. The piezoelectric properties of PMN-PT ceramics with glass frit addition are strongly dependent on the densification. The addition of glass frits into PMN-PT matrix reduced the sintering temperature to 1 100℃ instead of 1 150 ℃ for samples without glass. The piezoelectric coefficients (d33) of PMN-PT textured ceramics achieved 568 pc/N with 1 wt% excess PbO.