The SiCf/SiC composites containing PyC interphase were prepared by chemical vapor infiltration process. The influences of thermal oxidation on the complex permittivity and microwave absorption properties of Si Cf/Si C composites were investigated in the frequency range of 8.2-12.4 GHz. Both the real and imaginary parts of the complex permittivity decreased after thermal oxidation. The composites after 100 h thermal oxidation showed that reflection loss exceeded-10 d B in the frequency of 9.7-11.9 GHz and the minimum value was-11.4 d B at 11.0 GHz. The flexural strength of composites decreased but fracture behavior was improved obviously after thermal oxidation. These results indicate that the SiCf/SiC composites containing PyC interphase after thermal oxidation possess good microwave absorbing property and fracture behavior.
The effects of dwell time on the phase structure, microstructure, and electrical properties were investigated for the 0.98(K0.sNa0.5)NbO3-0.02LaFeO3 ceramics (abbreviated as 0.98KNN-0.02LF). All the ceramics sintered for different dwell time are of pure phase and the peak intensity of the 0.98KNN-0.02LF ceramics becomes stronger with a longer dwell time. Denser microstructures with larger grain size are developed for the sample with a longer dwell time. The maximum dielectric permittivity decreases with increasing the dwell time, and the deteriorative dielectric properties are due to the increasing grain size and the domain wall motion. Ferroelectric properties results indicate that 2Pr value slightly decreases with increasing the dwell time, while the 2Ec value increases. Consequently, the 0.98KNN-0.02LF ceramic sintered at 1150 ℃ for 2 h shows optimum dielectric properties (er=2253 and tan fi〈5%) and ferroelectric properties (2Pr=34.51 gC/cm2 and 2Ec=5.07 kV/mm).
The pyrolytic carbon (PyC) coatings were fabricated on A1203 fiber fabrics by the method of chemical vapor deposition (CVD). The microstructures of A1203 fibers with and without PyC coatings were characterized by SEM and Raman spectroscopy. The influence of deposition time of PyC on the DC conductivity (ad) of A1203 filaments and complex permittivity of fabrics at X band (8.2-12.4 GHz) were investigated. The values of Crd and complex permittivity increase with increasing deposition time of PyC. The electron relaxation polarization and conductance loss were supposed to be contributed to the increase of ε' and ε", respectively. In addition, the reflection loss (RL) of fabrics was calculated. The results show that the microwave absorbing properties of Al2O3 fiber fabrics can be improved by PyC coatings. The best RL results are for 60 min-deposition sample, of which the minimum value is about -40.4 dB at about 9.5 GHz and the absorbing frequency band (AFB) is about 4 GHz.