您的位置: 专家智库 > >

国家自然科学基金(s11179030)

作品数:1 被引量:0H指数:0
发文基金:国家自然科学基金更多>>
相关领域:天文地球更多>>

文献类型

  • 1篇中文期刊文章

领域

  • 1篇天文地球

主题

  • 1篇RAMAN_...
  • 1篇X-RAY_...
  • 1篇CHARAC...
  • 1篇FIRST-...
  • 1篇DISPLA...

传媒

  • 1篇Chines...

年份

  • 1篇2012
1 条 记 录,以下是 1-1
排序方式:
First-order character of the displacive structural transition in BaWO_4
2012年
Nearly all displacive transitions have been considered to be continuous or second order, and the rigid unit mode (RUM) provides a natural candidate for the soft mode. However, in-situ X-ray diffraction and Raman measurements show clearly the first-order evidences for the scheelite-to-fergusonite displacive transition in SaWO4: a 1.6% volume collapse, coexistence of phases, and hysteresis on release of pressure. Such first-order signatures are found to be the same as the soft modes in BaWO4, which indicates the scheelite-to-fergusonite displacive phase transition hides a deeper physical mechanism. By the refinement of atomic displacement parameters, we further show that the first-order character of this phase transition stems from a coupling of large compression of soft BaOs polyhedrons to the small displacive distortion of rigid WO4 tetrahedrons. Such a coupling will lead to a deeper physical insight in the phase transition of the common scheelite-structured compounds.
谭大勇肖万生周微陈鸣熊小林宋茂双
共1页<1>
聚类工具0