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国家自然科学基金(s20174031)

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EFFECT OF MORPHOLOGICAL STRUCTURE OF AMINOMETHYL POLYSTYRENE RESIN ON THE CATALYTIC PROPERTIES OF POLYMERSUPPORTED RUTHENIUM COMPLEXES
2009年
Polymer-supported ruthenium complexes ■-Phen-Ru-①,■-Phen-Ru-②,■-Phen-Ru-③,■-Phen-Ru-④, ■-Phen-Ru-⑤,■-Phen-Ru-⑥and ■-Phen-Ru-⑦were prepared using aminomethyl polystyrenes of different morphological structures as supports.A variety of alcohols were oxidized efficiently into the corresponding ketones, carboxylic acids or aldehydes with iodosylbenzene (PhIO) catalyzed by aminomethyl polystyrene-supported ruthenium complexes under mild reaction conditions in acetonitrile.The influences of morphological structure...
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