The main results obtained from the experimental and engineering investigation on the heat evolution and cracking risk of a furnace concrete block were presented. The heat evolution of experimental mortars containing micro-slag under different environmental temperatures was instrumented in order to investigate the self-catalyzed effect, which was discovered in engineering. More-over,the thermal stress of the furnace concrete due to heat temperature rise was calculated to evaluate the cracking risk of mass concrete containing micro-slag due to self-catalyzed effect. The experimental results illustrate that with the development of hydration and initial temperature of mixture, the hydra-tion can be also accelerated and temperature of concrete will be continued to rise, which was the self-catalyzed effect. And the thermal stress due to self-catalyzed effect could not result in the cracking of furnace concrete.