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国家自然科学基金(60801022)

作品数:5 被引量:14H指数:2
相关作者:刘卫华朱长纯商世广党涛更多>>
相关机构:西安交通大学西安邮电学院更多>>
发文基金:国家自然科学基金中国航空科学基金国家高技术研究发展计划更多>>
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Synthesis of CNT film on the surface of micro-pyramid array and its intense pulsed emission characteristics被引量:10
2012年
We developed a new scheme to suppress the electric-field-screening effect in high growth density of a carbon nanotube(CNT) film during its intense pulsed emission.We synthesize the CNT film on a tridimensional surface(t-CNT film).The tridimensional surface includes wet etched silicon pyramids,and the Ni layer is electroless plated thereon.The intense pulsed emission characteristics of the t-CNT and planar-grown CNT(p-CNT) films were measured using a diode structure in single-pulse mode.The even turn-on field decreased from 5.5 V/μm for p-CNTs to 2.8 V/m for t-CNTs,and the peak emission current increased from 232 A for p-CNTs to 324 A for t-CNTs at a peak field intensity ~12.2 V/m.The peak current of the t-CNT film increased by ~39.7% over the p-CNT film.It is clear that the micro-pyramid array can effectively suppress the field screening effect to improve the electron-emission of CNT films.
ZENG FanGuangLI XinLIU WeiHuaQIAO ShuZhenMA HuaLiZHANG RuiXIA LianShengCHEN YiLIU XingGuangZHANG Huang
关键词:碳纳米管膜强流脉冲碳纳米管薄膜
多皱纹纳米石墨片的制备及其工艺研究
2008年
在500℃下,采用PECVD法在以玻璃为衬底的多种金属镀层上成功制备出纳米石墨片。SEM分析表明,不同催化剂层上生长的二维纳米石墨片在形态上存在显著区别。在所涉及的工艺参数范围内,Ni/Zn复合金属镀层上二维纳米石墨片的生长效率最高,且在部分区域具有碳纳米墙形貌特征。TEM分析表明,所生长的二维纳米石墨片具有大量皱纹,且皱纹具有指纹形的石墨层状结构。纳米尺度的皱纹随机分布于整个二维纳米石墨片中,与超薄石墨烯自然形成的皱褶存在显著区别。根据指纹形皱纹的最大层数估计,石墨片的厚度在10nm左右,这种多皱纹纳米石墨片反映了催化剂对二维石墨生长的影响。这种材料除了可作为场发射冷阴极外,在催化剂载体以及气敏传感器等领域都可能有重要应用。
刘卫华党涛朱长纯
Improvement in the intense pulsed emission stability of grown CNT films via an electroless plated Ni layer被引量:7
2011年
Carbon nanotube(CNT)films were grown on silicon wafers with and without a nickel layer(Si-CNT and Ni-CNT)via the pyrolysis of iron phthalocyanine.The nickel layer was prepared using the electroless plating method.To study the emission stability of Si-CNT and Ni-CNT cathodes during intense pulsed emission,emission characteristics were measured repeatedly with a diode structure using a Marx generator as a voltage source.For the peak values of the pulsed voltage,which were in the range between 1.62-1.66 MV(corresponding to electric field intensities between 11.57-11.85 V/μm),the first cycle emission current was 109.4 A for Si-CNT and 180.5 A for Ni-CNT.By comparing the normalized emission currents of the Si-CNT and Ni-CNT cathodes,the improvement in the emission stability can be easily quantified.The number of emission cycles necessary for the peak current to decay from 100%to 50%increased from^3 for Si-CNT to^11 for a Ni-CNT film.
ZENG FanGuangLI XinLIU WeiHuaQIAO ShuZhenMA HuaLiZHANG RuiXIA LianShengCHEN YiLIU XingGuangZHANG Huang
关键词:化学镀镍层发射电流碳纳米管阴极MARX发生器
Laser tuned field emission of the carbon nanotube arrays grown on an optical fiber被引量:1
2014年
Laser was coupled into an optical fiber,on which covered a layer of well-aligned carbon nanotubes(CNTs)serving as cathode,to tune the field emission of the cathode.CNT arrays as field emission cathode were synthesized by chemical vapor deposition(CVD)on a naked fiber core.When the laser was coupled into the fiber,the turn-on voltage(Vto at a current density of 1 mA cm?2)decreased from 1.0 to 0.9 kV and the emission current density increased from 0.83 mA cm?2(at a 1 kV bias voltage)to3.04 mA cm?2 on 40μm diameter fiber.A photon absorption mechanism is attributed to the field emission improvement.The estimated effective work function of CNT arrays on the optical fiber decrease from 4.89 to 4.29 eV.The results show the possibility of constructing a waveguide type laser modulated field emission cathode.
WEI XianQiLI XinLIU WeiHuaWANG XiaoLi
关键词:LASER
石墨烯折角可控场发射的研究
低维的碳纳米材料是一类重要的纳米冷阴极材料,如单壁和多壁碳纳米管,碳纳米墙等。石墨烯作为一种理想的二维材料,其场发射性能也受到广泛关注。由于石墨烯通常平躺于基底上,为了提高其场发射性能,通常需要将石墨烯边沿直立起来或构造...
刘卫华庞凯歌田康魏仙奇李昕王小力
关键词:真空电子学
电介质TiO2粉体增强印刷碳纳米管薄膜的场发射性能
2010年
提出了一种可显著改善丝网印刷碳纳米管(CNTs)薄膜场发射特性的浆料制备方法。该方法以乙基纤维素为制浆剂,松油醇为溶剂,通过超声波把CNTs和TiO2粉体均匀地分散成CNTs/TiO2复合浆料,扫描电镜表明,丝网印刷的CNTs/TiO2薄膜在高温下烧结后形成连续的膜体,CNTs被球状的TiO2颗粒均匀隔离;场发射特性测试表明,与单纯的CNTs薄膜相比,CNTs/TiO2薄膜的开启电场降低了0.2V/μm,在电场强度为4.0V/μm时电流密度增加了26.5μA/cm2,结果说明,该方法对于提高CNTs的场发射特性有明显的作用,在CNTs发射显示器的制作中有很好的实际应用价值。
商世广刘卫华
关键词:碳纳米管场发射丝网印刷
多皱纹纳米石墨片的制备及其工艺研究
在500℃下,采用PECVD法在以玻璃为衬底的多种金属镀层上成功制备出纳米石墨片。SEM分析表明,不同催化剂层上生长的二维纳米石墨片在形态上存在显著区别。在所涉及的工艺参数范围内,Ni/Zn复合金属镀层上二维纳米石墨片的...
刘卫华党涛朱长纯
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光纤表面覆盖碳纳米管冷阴极的光耦合场发射
本文采用高温催化热解化学气相沉积法在光纤上生长碳纳米管,研究了激光波长为375nm的光辅助场对碳纳米管场发射特性的影响。实验结果表明,光纤表面覆盖着垂直生长的碳纳米管,该结构的场发射冷阴极降低了碳管发射尖端的电场屏蔽效应...
魏仙奇李昕庞凯歌刘卫华王小力
关键词:碳纳米管光纤场发射光耦合
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