The structure and characteristics of CdTe thin filrns are closely dependent on the whole deposition process in close-space sublimation (CSS). The physical mechanism of CSS was analyzed aud the temperature distribution in CSS system was measured, and the influences of the increasing-temperature process and pressure on the preliminary nucleus creation were studied. The resuits indicate : tire samples deposited at different pressures hare a cubical structure of CdTe and the diffraction peaks of CdS and SnO2 : F. As the atmosphere pressure increases, the crystal size of CdTe decreases, the rate of the transparency of the thin film decreases and the absorption side moves towards the short-wave direction. After a 4-minute depositing process with a substrate teraw.rature of 500℃ and a source temperature of 620 ℃, the polycostallinc thin films can be mmade , so the production of high-quality integrated cell with StrO2: F/ CdS/ CdTe/ Au structure is hopeful.