In the framework of systematic science of alloys,the average molar property(volume and potential energy) functions of disordered alloys were established.From these functions,the average molar property functions,partial molar property functions,derivative functions with respect to composition,general equation of relationship between partial and average molar properties of components,difference equation and constraining equation of different values between partial and average molar properties,as well as general Gibbs-Duhem formula were derived.It was proved that the partial molar properties calculated from various combinative functions of average molar properties of alloys are equal,but in general,the partial molar properties are not equal to the average molar properties of a given component.This means that the partial molar properties cannot represent the corresponding properties of the component.All the equations and functions established in this work were proved to be correct by calculating the results of partial and average atomic volumes of components as well as average atomic volumes of alloys in the Au-Ni system.
In this paper,it is pointed out that the descriptions of alloy phase structures are dependent on structural unit sequence.In the systematic science of alloys(SSA),the alloy phase structures are described by means of the symmetry element sequence combining with characteristic atom sequence.It is named the characteristic atom arranging structure,which can display the characteristic atoms at the lattice sites and the micro-inhomogeneity,besides the symmetry.Each characteristic atom has its own characters:neighboring configuration,potential energy,volume and electronic structure.The micro-inhomogeneity of alloy phases can be described by concentrations and short-range ordered parameters of characteristic atoms.The differences between the electronic structures of alloy phases and electronic structures of characteristic atoms in the alloy phases are also discussed.
XIE YouQing1,2,3,LIU XinBi1,2,3,PENG HongJian4,NIE YaoZhuang5,LI XiaoBo6 & LI YanFen1,2,3 1 School of Materials Science and Engineering,Central South University,Changsha 410083,China